Crystal structure of (1,3-di-tert-butyl-eta5-cyclopentadienyl)trimethylhafnium(IV)

Authors
Pérez Redondo, AdriánUniversity of Alcalá Author; Yélamos Sánchez, CarlosUniversity of Alcalá Author; Varela Izquierdo, Víctor
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/35839
DOI: 10.1107/S205698901500585X
ISSN: 2056-9890
Date
2015-04-02
Affiliation
Universidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica
Funders
Ministerio de Educación y Ciencia de España
Bibliographic citation
Acta Crystallographica Section E (Crystallographic Communications), 2015, v. 71, n. 5, p. m100-m101
Keywords
crystal structure
hafnium
cyclopentadienyl ligand
organometallic compound
Project
Factoría de Cristalización CONSOLIDER-INGENIO 2010 CSD2006-00015
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Rights
Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
Access rights
info:eu-repo/semantics/openAccess
Share
 
Abstract
The mol. of the title organometallic hafnium(IV) compd., [Hf(CH3)​3(C13H21)​] or [HfMe3(η5-​C5H3-​1,​3-​tBu2)​]​, adopts the classical three-​legged piano-​stool geometry for monocyclopentadienylhafnium(IV) derivs. with the three Me groups bonded to the Hf(IV) atom at the legs. The C atoms of the two tert-​Bu group bonded to the cyclopentadienyl (Cp) ring are 0.132 (5) and 0.154 (6) Å above the Cp least-​squares plane. There are no significant intermol. interactions present between the mols. in the crystal structure.
Files in this item
Collections
Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
Este ítem está sujeto a una licencia Creative Commons.