Show simple item record

dc.contributor.authorPérez Redondo, Adrián 
dc.contributor.authorYélamos Sánchez, Carlos 
dc.contributor.authorVarela Izquierdo, Víctor
dc.date.accessioned2019-02-08T11:02:50Z
dc.date.available2019-02-08T11:02:50Z
dc.date.issued2015-04-02
dc.identifier.bibliographicCitationActa Crystallographica Section E (Crystallographic Communications), 2015, v. 71, n. 5, p. m100-m101en
dc.identifier.issn2056-9890
dc.identifier.urihttp://hdl.handle.net/10017/35839
dc.description.abstractThe mol. of the title organometallic hafnium(IV) compd., [Hf(CH3)​3(C13H21)​] or [HfMe3(η5-​C5H3-​1,​3-​tBu2)​]​, adopts the classical three-​legged piano-​stool geometry for monocyclopentadienylhafnium(IV) derivs. with the three Me groups bonded to the Hf(IV) atom at the legs. The C atoms of the two tert-​Bu group bonded to the cyclopentadienyl (Cp) ring are 0.132 (5) and 0.154 (6) Å above the Cp least-​squares plane. There are no significant intermol. interactions present between the mols. in the crystal structure.en
dc.description.sponsorshipMinisterio de Educación y Ciencia de Españaes_ES
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.rightsAttribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)en
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/4.0/en
dc.subjectcrystal structureen
dc.subjecthafniumen
dc.subjectcyclopentadienyl liganden
dc.subjectorganometallic compounden
dc.titleCrystal structure of (1,3-di-tert-butyl-eta5-cyclopentadienyl)trimethylhafnium(IV)en
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaQuímicaes_ES
dc.subject.ecienciaChemistryen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Orgánica y Química Inorgánicaes_ES
dc.date.updated2019-02-08T11:01:05Z
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1107/S205698901500585X
dc.relation.projectIDinfo:eu-repo/grantAgreement/CAICYT/Plan Nacional de I+D+i 2008-2011/CSD2006-00015/ES/FACTORÍA DE CRISTALIZACIÓNes_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen
dc.identifier.uxxiAR/0000021215
dc.identifier.publicationtitleActa Crystallographica Section E (Crystallographic Communications)en
dc.identifier.publicationvolume71
dc.identifier.publicationlastpagem101
dc.identifier.publicationissue5
dc.identifier.publicationfirstpagem100


Files in this item

Thumbnail

This item appears in the following Collection(s)

Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
Este ítem está sujeto a una licencia Creative Commons.