RT info:eu-repo/semantics/article
T1 Crystal structure of (1,3-di-tert-butyl-eta5-cyclopentadienyl)trimethylhafnium(IV)
A1 Pérez Redondo, Adrián
A1 Yélamos Sánchez, Carlos
A1 Varela Izquierdo, Víctor
K1 crystal structure
K1 hafnium
K1 cyclopentadienyl ligand
K1 organometallic compound
K1 Química
K1 Chemistry
AB The mol. of the title organometallic hafnium(IV) compd., [Hf(CH3)​3(C13H21)​] or [HfMe3(η5-​C5H3-​1,​3-​tBu2)​]​, adopts the classical three-​legged piano-​stool geometry for monocyclopentadienylhafnium(IV) derivs. with the three Me groups bonded to the Hf(IV) atom at the legs.  The C atoms of the two tert-​Bu group bonded to the cyclopentadienyl (Cp) ring are 0.132 (5) and 0.154 (6) Å above the Cp least-​squares plane.  There are no significant intermol. interactions present between the mols. in the crystal structure.
SN 2056-9890
YR 2015
FD 2015-04-02
LK http://hdl.handle.net/10017/35839
UL http://hdl.handle.net/10017/35839
LA eng
NO Ministerio de Educación y Ciencia de España
DS MINDS@UW
RD 19-abr-2024