| dc.contributor.author | Sánchez Muñoz, Aránzazu | |
| dc.contributor.author | Núñez Ventura, Araceli | |
| dc.contributor.author | Álvarez-Builla Gómez, Julio | |
| dc.contributor.author | Burgos García, Carolina | |
| dc.date.accessioned | 2009-10-02T11:20:36Z | |
| dc.date.available | 2009-10-02T11:20:36Z | |
| dc.date.issued | 2004 | |
| dc.identifier.bibliographicCitation | Tetrahedron, 2004, v. 60, n. 51, p. 11843-11850 | en |
| dc.identifier.issn | 0040-4020 | |
| dc.identifier.uri | http://hdl.handle.net/10017/4190 | |
| dc.description.abstract | Tris(trimethylsilyl)silane (TTMSS) and azobisisobutironitrile (AIBN) promote the intramolecular heteroarylation of arenesulfonamides with pyridyl radicals under thermal conditions. The arenesulfonamides are easily prepared from pyridinium N-2′-pyridylaminide. The heteroarylation process involves pyridyl radical cyclization and ipso substitution. | en |
| dc.description.sponsorship | Financial support by the Comisión Interministerial de
Ciencia y Tecnología (CICYT, project BQU2001-1508)
and two grants, by the Universidad de Alcalá (A. S.) and
by Ministerio de Educación y Ciencia (Spain) (A. N.) are
gratefully acknowledged. | en |
| dc.format.mimetype | application/pdf | en |
| dc.language.iso | eng | en |
| dc.publisher | Elsevier | en |
| dc.rights | (c) Elsevier, 2004 | en |
| dc.subject | Arylation | en |
| dc.subject | Biaryls | en |
| dc.subject | Ipso-substitution mechanism | en |
| dc.subject | Radicals and radical reaction | en |
| dc.subject | Tris(trimethylsilyl)silane | en |
| dc.title | Pyridinium N-2´-pyridylaminide: synthesis of 3-aryl-2-aminopyridines through an intramolecular radical process | en |
| dc.type | info:eu-repo/semantics/article | en |
| dc.subject.eciencia | Ciencia | es_ES |
| dc.subject.eciencia | Química orgánica | es_ES |
| dc.subject.eciencia | Science | en |
| dc.subject.eciencia | Chemistry, organic | en |
| dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Orgánica | |
| dc.relation.publisherversion | http://dx.doi.org/10.1016/j.tet.2004.09.099 | |
| dc.type.version | info:eu-repo/semantics/publishedVersion | en |
| dc.identifier.doi | 10.1016/j.tet.2004.09.099 | |
| dc.relation.projectID | BQU2001-1508 (Comisión Interministerial de Ciencia y Tecnología-CICYT) | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |
