Synthesis of BN-Polyarenes by a Mild Borylative Cyclization Cascade
Authors
Sans Panadés, Ester; Vaquero López, Juan José; Fernández Rodríguez, Manuel Ángel; García García, PatriciaIdentifiers
Permanent link (URI): http://hdl.handle.net/10017/59159DOI: 10.1021/acs.orglett.2c02477
ISSN: 1523-7060
Date
2022-08-01Funders
Ministerio de Ciencia e Innovación
Instituto de Salud Carlos III
Bibliographic citation
Organic Letters, 2022, v. 24, n. 31, p. 5860-5865
Project
info:eu-repo/grantAgreement/MICINN//PID2020-115128RB-I00/ES/
info:eu-repo/grantAgreement/ISCIII//RICORS2040%2FRD21%2F0005%2F0016/ES/
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Rights
© The Authors
Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
Access rights
info:eu-repo/semantics/openAccess
Abstract
Reaction of BCl3 with suitably substituted o-alkynylanilines promotes a cascade reaction in which BN-polycyclic compounds are obtained via the formation of two new cycles and three new bonds in a single operational step. The reaction is highly efficient and takes place at room temperature, providing a very mild and straightforward strategy for the preparation of BN-aromatic compounds, which can be further transformed into a variety of BN-PAHs with different polycyclic cores and substituents.
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Synthesis_Sans_OrgLett_2022.pdf | 1.466Mb |
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Synthesis_Sans_OrgLett_2022.pdf | 1.466Mb |
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