dc.contributor.author | Royo Gracia, Pascual | |
dc.contributor.author | Vázquez de Miguel, Amelio | |
dc.date.accessioned | 2009-11-12T12:58:14Z | |
dc.date.available | 2009-11-12T12:58:14Z | |
dc.date.issued | 1981 | |
dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1981, v.205, n.2, p.223-228 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | http://hdl.handle.net/10017/4814 | |
dc.description.abstract | Passage of CO through solutions of complexes (C6F5)2CoL2 gives carbonyl derivatives (C6F5)2CoL2(CO) (L2 = 2PEt3, 2P-n-Bu3, 2PPh3, Ph2PCH2CH3PPh2). The properties of these compounds are described.
The compounds are also produced by treating solutions of (C6F5)2Co-(dioxane)2 with CO, but a simultaneous reduction to (C6F5)Co(CO)4 takes place. Treatment of the latter complex with monodentate ligands gives substitution products (C6F5)Co(CO)3L (L = PEt3, P-n-Bu3, PPh3) all of which are monomeric, whereas the addition of Ph2PCH2CH2PPh2 gives the dimer (C6F5)(CO)2CoL-LCo(CO)2(C6F5). The properties of these compounds are discussed. | en |
dc.description.sponsorship | Ministerio de Educación y Ciencia | es_ES |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | © Elsevier, 1981 | en |
dc.subject | Carbonyl-organocobalt(I) | en |
dc.subject | Carbonyl-organocobalt(II) | en |
dc.title | Carbonyl-organocobalt(I) and carbonyl-organocobalt(II) complexes | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/S0022-328X(00)81479-5 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/S0022-328X(00)81479-5 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |