| dc.contributor.author | Gómez Rubio, Manuel | |
| dc.contributor.author | Royo Gracia, Pascual | |
| dc.contributor.author | Selas Pérez, José Manuel | |
| dc.date.accessioned | 2009-11-12T09:46:49Z | |
| dc.date.available | 2009-11-12T09:46:49Z | |
| dc.date.issued | 1986 | |
| dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1986, v. 314, p. 131-138 | en |
| dc.identifier.issn | 0022-328X | |
| dc.identifier.uri | http://hdl.handle.net/10017/4789 | |
| dc.description.abstract | The reaction of the compounds TaXCl4 (X = η5-C5H5, η5-C5H4SiMe3 or Cl) with o-diphenols 4-RC6H3(OH)2 (R = H, Me, But gave the dialkoxides XCl2Ta(O2C6H3R), whereas the reaction with 4,4′-isopropylidenediphenol gave the monoalkoxides [TaXCl3]2[(OC6H4)2CMe2]. Osmometry shows the cyclopentadienyl derivatives with X = η-C5H4SiMe3 and R = Me, But to be dimeric in benzene, but the halogeno complex with X = Cl and R = But to be trimeric. The new alkoxide complexes have been characterised by IR and 1H and 13C NMR spectroscopy. | en |
| dc.format.mimetype | application/pdf | en |
| dc.language.iso | eng | en |
| dc.publisher | Elsevier | en |
| dc.rights | (c) Elsevier, 1986 | en |
| dc.subject | Phenoxotantalum(V) | en |
| dc.title | Phenoxotantalum(V) complexes | en |
| dc.type | info:eu-repo/semantics/article | en |
| dc.subject.eciencia | Ciencia | es_ES |
| dc.subject.eciencia | Química inorgánica | es_ES |
| dc.subject.eciencia | Science | en |
| dc.subject.eciencia | Chemistry, inorganic | en |
| dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
| dc.relation.publisherversion | http://dx.doi.org/10.1016/0022-328X(86)80358-8 | |
| dc.type.version | info:eu-repo/semantics/publishedVersion | en |
| dc.identifier.doi | 10.1016/0022-328X(86)80358-8 | |
| dc.relation.projectID | 2001-83 (Ministerio de Educación y Ciencia) | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |
