(C5Me5)SiMe3 as a mild and effective reagent for transfer of the C5Me5 ring: an improved route to monopentamethylcyclopentadienyl trihalides of the group-4 elements

Authors
Hidalgo Llinás, Gerardo; Mena Montoro, MiguelUniversity of Alcalá Author; Palacios Gragera, Federico FernandoUniversity of Alcalá Author; Royo Gracia, PascualUniversity of Alcalá Author; Serrano Roche, Ricardo
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4653
DOI: 10.1016/0022-328X(88)80551-5
ISSN: 0022-328X
Publisher
Elsevier
Date
1988
Affiliation
Universidad de Alcalá. Departamento de Química Inorgánica
Bibliographic citation
Journal of Organometallic Chemistry, 1988, v. 340, n. 1, p. 37-40
Keywords
Monopentamethylcyclopentadienyl trihalides
Project
2001/83 (CAICYT)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/0022-328X(88)80551-5
Rights
© Elsevier, 1988
Access rights
info:eu-repo/semantics/openAccess
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Abstract
The reaction between (C5Me5)SiMe3 and group 4 element tetrahalides MX4 (M=Ti, X=Cl, Br, I; M=Zr and Hf, X=Cl) gives the corresponding (η5-C5Me5)MX3 derivatives in nearly quantitative yields in a one-step procedure without the need for further purification.
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