| dc.contributor.author | Petrisor, Cristina Elena | |
| dc.contributor.author | Royo Cantabrana, Eva | |
| dc.contributor.author | Cuenca Agreda, José Tomás | |
| dc.contributor.author | Gómez-Bengoa, Enrique | |
| dc.date.accessioned | 2009-09-08T11:32:41Z | |
| dc.date.available | 2009-09-08T11:32:41Z | |
| dc.date.issued | 2009 | |
| dc.identifier.bibliographicCitation | Organometallics, 2009, v. 28, p. 4165-4169 | en |
| dc.identifier.issn | 0276-7333 | |
| dc.identifier.uri | http://hdl.handle.net/10017/3832 | |
| dc.description.abstract | New η5-cyclopentadienyl-η1-amido monoalkyl zirconium compounds of the type [ZrR(η5-
C5H4SiMe2-η1-NtBu)(η5-C5H4R0)] (R = Me, Bn; R0 =H, SiMe3, SiMe2CH2CHdCH2) have been
synthesized and fully characterized. Allyldimethylsilylcyclopentadienyl derivatives [ZrR(η5-C5H4SiMe2-η1-NtBu)(η5-C5H4SiMe2CH2CHdCH2)] isomerize the allyl fragment bound to the
cyclopentadienyl ring to give the corresponding [ZrR(η5-C5H4SiMe2-η1-NtBu)(η5-C5H4SiMe2CHdCHCH3)] compounds (R=Me, Bn). Experimental as well as DFT computational studies support an isomerization mechanism based on a N-assisted 1,3-proton shift. | en |
| dc.format.mimetype | application/pdf | en |
| dc.language.iso | eng | en |
| dc.publisher | ACS Journal Publishing | en |
| dc.rights | © American Chemical Society, 2009 | en |
| dc.subject | Isomerización | en |
| dc.subject | Organometálicos | en |
| dc.subject | Zirconio | en |
| dc.title | Amidosilylcyclopentadienyl monoalkyl zirconium compounds: evidence
of a N-assisted 1,3-proton shift olefin isomerization mechanism | en |
| dc.type | info:eu-repo/semantics/article | en |
| dc.subject.eciencia | Ciencia | es_ES |
| dc.subject.eciencia | Química inorgánica | es_ES |
| dc.subject.eciencia | Science | en |
| dc.subject.eciencia | Inorganic chemistry | en |
| dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
| dc.relation.publisherversion | http://dx.doi.org/10.1021/om900296a | |
| dc.type.version | info:eu-repo/semantics/publishedVersion | en |
| dc.identifier.doi | 10.1021/om900296a | |
| dc.relation.projectID | MAT2007-60997 (Ministerio de Educación y Ciencia) | |
| dc.relation.projectID | S-0505/PPQ/0328 (Comunidad de Madrid) | |
| dc.relation.projectID | CCG08-UAH/PPQ-4026 (Universidad de Alcalá) | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |
