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dc.contributor.authorPetrisor, Cristina Elena 
dc.contributor.authorRoyo Cantabrana, Eva 
dc.contributor.authorCuenca Agreda, Tomás
dc.contributor.authorGómez-Bengoa, Enrique
dc.date.accessioned2009-09-08T11:32:41Z
dc.date.available2009-09-08T11:32:41Z
dc.date.issued2009
dc.identifier.bibliographicCitationOrganometallics, 2009, v. 28, p. 4165-4169en
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/10017/3832
dc.description.abstractNew η5-cyclopentadienyl-η1-amido monoalkyl zirconium compounds of the type [ZrR(η5- C5H4SiMe2-η1-NtBu)(η5-C5H4R0)] (R = Me, Bn; R0 =H, SiMe3, SiMe2CH2CHdCH2) have been synthesized and fully characterized. Allyldimethylsilylcyclopentadienyl derivatives [ZrR(η5-C5H4SiMe2-η1-NtBu)(η5-C5H4SiMe2CH2CHdCH2)] isomerize the allyl fragment bound to the cyclopentadienyl ring to give the corresponding [ZrR(η5-C5H4SiMe2-η1-NtBu)(η5-C5H4SiMe2CHdCHCH3)] compounds (R=Me, Bn). Experimental as well as DFT computational studies support an isomerization mechanism based on a N-assisted 1,3-proton shift.en
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherACS Journal Publishingen
dc.rights© American Chemical Society, 2009en
dc.subjectIsomerizaciónen
dc.subjectOrganometálicosen
dc.subjectZirconioen
dc.titleAmidosilylcyclopentadienyl monoalkyl zirconium compounds: evidence of a N-assisted 1,3-proton shift olefin isomerization mechanismen
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaCIENCIAes_ES
dc.subject.ecienciaQuímica inorgánicaes_ES
dc.subject.ecienciaSCIENCEen
dc.subject.ecienciaInorganic chemistryen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Inorgánica
dc.relation.publisherversionhttp://dx.doi.org/10.1021/om900296a
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1021/om900296a
dc.relation.projectIDMAT2007-60997 (Ministerio de Educación y Ciencia)
dc.relation.projectIDS-0505/PPQ/0328 (Comunidad de Madrid)
dc.relation.projectIDCCG08-UAH/PPQ-4026 (Universidad de Alcalá)
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen


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