RT info:eu-repo/semantics/article
T1 Preparation of the compounds (µ-O)[Ti(C5Me5)R2]2, (R=Me, CH2Ph, or CH2SiMe3) and the cristal structure of the derivative with                              R=CH2SiMe3
A1 Gómez Sal, Pilar
A1 Mena Montoro, Miguel
A1 Palacios Gragera, Federico Fernando
A1 Royo Gracia, Pascual
A1 Serrano Roche, Ricardo
A1 Martínez Carrera, Sagrario
K1 (µ-O)[Ti(C5Me5)R2]2
K1 R=Me
K1 CH2Ph
K1 CH2SiMe3
K1 R=CH2SiMe3
K1 Ciencia
K1 Química inorgánica
K1 Science
K1 Chemistry, inorganic
AB The complex (μ-O)[Ti(C5Me5)Cl2]2 can be readily alkylated with organo-lithium or -magnesium reagents to give (μ-O)[Ti(C5Me5)R2]2 (R = Me, Ch2Ph, or CH2SiMe3) compounds which have been characterized by analytical and spectroscopic methods and, in the case of R = CH2SiMe3, by an X-ray diffraction study. Crystals are trigonal, space group PFull-size image (<1 K)C1 (no. 165); the values of R and Rw were 0.063 and 0.086 respectively. The compound has a crowded structure with a Ti-O-Ti angle of 155.9(1)°, and possibly with Ti…H-C interactions.
PB Elsevier
SN 0022-328X
YR 1989
FD 1989
LK http://hdl.handle.net/10017/4641
UL http://hdl.handle.net/10017/4641
LA eng
DS MINDS@UW
RD 29-abr-2024