RT info:eu-repo/semantics/article
T1 The molecular structure of Me3TiCp* in the gas phase
A1 Blom, R.
A1 Rypdal, K.
A1 Mena Montoro, Miguel
A1 Royo Gracia, Pascual
A1 Serrano Roche, Ricardo
K1 Gas phase electron diffraction
K1 GED
K1 Methyl groups
K1 Ciencia
K1 Química inorgánica
K1 Science
K1 Chemistry, inorganic
AB The thermal average molecular structure of Me3TiCp★ has been determined by gas phase electron diffraction (GED). The GED data are consistent with a molecular model in which the TiMe3 fragment has C3v symmetry and the TiCp★ fragment has C5v symmetry. No static tilt of the methyl groups attached to titanium can be detected, although a flattening of the methyl groups with Ti-C-H 103.8(1.2)° is obtained. The Ti-C(Me) bond distance is 210.7(5) pm, and the Ti-C(Cp★) distance 238.0(5) pm.
PB Elsevier
SN 0022-328X
YR 1990
FD 1990
LK http://hdl.handle.net/10017/4633
UL http://hdl.handle.net/10017/4633
LA eng
NO Norwegian Research Council for Science and Humanities
DS MINDS@UW
RD 01-may-2024