RT info:eu-repo/semantics/article
T1 Yttrium and Erbium Halide Complexes with [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)] as a Neutral Tridentate Ligand
A1 Caballo González, Jorge
A1 García Castro, María
A1 Martín Alonso, Avelino
A1 Mena Montoro, Miguel
A1 Pérez Redondo, Adrián
A1 Yélamos Sánchez, Carlos
K1 Química
K1 Chemistry
AB Treatment of [{TiCp*(mu-NH)}(3)(mu(3)-N)] (1; Cp* = eta(5)-C5Me5) with yttrium and erbium halide complexes [MCl3(THF)(3.5)] and [MCpCl2(THF)(3)] (Cp = eta(5)-C5H5) gives cube-type adducts [Cl3M{(mu(3)-NH)(3)Ti3Cp*(3)(mu(3)-N)}] and [CPCl2M{(mu(3)-NH)(3)Ti3Cp*(3)(mu(3)-N)}]. An analogous reaction of 1 with [{MCp2Cl}(2)] in toluene affords [Cp3M(mu-Cl)ClCpM{(mu(3)-NH)(3)Ti3Cp*(3)(mu(3)-N)}] (M = Y, Er).
SN 0020-1669
YR 2008
FD 2008-08-18
LK http://hdl.handle.net/10017/38626
UL http://hdl.handle.net/10017/38626
LA eng
NO Ministerio de Educación y Ciencia de España, Comunidad de Madrid, Universidad de Alcalá
DS MINDS@UW
RD 27-abr-2024