Neutral and cationic pentafluorophenylnickel(II) complexes
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4891DOI: 10.1016/S0022-328X(00)83530-5
ISSN: 0022-328X
Publisher
Elsevier
Date
1977Funders
We greatly appreciate financial support from Comisión Asesora de Investiga
ción Cientifica y Tecnica (Spain).
Bibliographic citation
Journal of Organometallic Chemistry, 1977, v. 137, n. 2, p. 229-234
Keywords
Pentafluorophenylnickel(II) complexes
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/S0022-328X(00)83530-5Rights
(c) Elsevier, 1977
Access rights
info:eu-repo/semantics/openAccess
Abstract
Metathetical reactions of Br(C6F5)Ni(PPh3)2 with metal salts MX (NaI, NaNO2, NaNO3, KCN, KSCN, AgClO4) have given the corresponding X(C6F5)Ni(PPh3)2 complexes. The perchlorate group of the complex (O3ClO)Ni(C6F5)(PPh3)2 is readily displaced. In this way cationic complexes [(C6F5)Ni(PPh3)2L]ClO4 have been prepared with L --- PPh3, PEt3, P-t-Bu3, AsPh3, C5H5N, OPPh3, SPPh3, H2O, or CH3NO2.
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