dc.contributor.author | Otero Montero, Antonio | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.date.accessioned | 2009-11-12T13:15:36Z | |
dc.date.available | 2009-11-12T13:15:36Z | |
dc.date.issued | 1978 | |
dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1978, v.154, n.1, p.13-19 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | http://hdl.handle.net/10017/4817 | |
dc.description.abstract | The chemical behaviour of (C6F5)3Sb (I), has been studied. Attempts to isolate transition-metal complexes of I were unsuccessful. Hydrolysis of I gives the binuclear [(C6F5)2Sb]2O (II) and treatment of I with chlorine, thallic chloride or copper(II) chloride gives (C6F5)3SbCl2 (III). Reactions of III with AgNO3, AgClO4 and NaOCH3 give disubstituted compounds of the type (C6F5)3SbX2 (IV, X = NO3; V, X = ClO4; VI, X = OCH3. Reactions of III with sodium acetylacetonate and sodium oxinate gives the monosubstituted octahedral complexes (C6F5)3SbCl-Acac (VII) and (C6F5)3SbClOx (VIII). Compounds VI–VIII are insoluble in water whereas compounds III–IV are hydrolysed to the binuclear derivatives [(C6F5)3SbX]2O (IX, X = Cl; X, X = NO3), and V similarly gives {[C6F5)3Sb]2O]} - (ClO4)2. | en |
dc.description.sponsorship | We greatly appreciate the award of a Research Fellowship (to A.O.) by the Ministerio de Educación
y Ciencia (Spain). | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | © Elsevier, 1978 | en |
dc.subject | Antimony | en |
dc.title | Pentafluorophenylantimony compounds | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/S0022-328X(00)82787-4 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/S0022-328X(00)82787-4 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |