dc.contributor.author | Antiñolo García, Antonio | |
dc.contributor.author | Fajardo, Mariano | |
dc.contributor.author | Otero Montero, Antonio | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.date.accessioned | 2009-11-12T11:44:54Z | |
dc.date.available | 2009-11-12T11:44:54Z | |
dc.date.issued | 1982 | |
dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1982, v. 234, p. 309-314 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | http://hdl.handle.net/10017/4811 | |
dc.description.abstract | The reduction of (η-C5H5)2NbCl2 (I) under various conditions gives the dimer (η-C5H5)4Nb2Cl3 (II) containing niobium(III) and niobium(IV). Reaction of II with AgClO4 gives [(η-C5H5)4Nb2Cl2]+ ClO4- (III). FeCl3 and (C6F5)2 TlBr displace I from II to give (η-C5H5)2Nb(μ-Cl)(μ-X)MY2, where MFe, XYCl(IV) and MTl, XBr, YC6F5 (V). Reactions of I with metal halides MXY2 give (η-C5H5)2ClNb(μ-Cl)MXY2 where XYCl, MAl (VI), Fe (VII), Tl (VIII) and XBr, YC6F5, MTl (IX). The chemical behaviour of all these compounds is described. | en |
dc.description.sponsorship | We greatly appreciate finantial support from Comisión Asesora de Investigación Científica y Técnica (Spain). | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | (c) Elsevier, 1982 | en |
dc.subject | Dicyclopentadienyl-niobium(III) | en |
dc.subject | Dicyclopentadienyl-niobium(IV) | en |
dc.title | Dicyclopentadienyl-niobium(III) and dicyclopentadienyl-niobium(IV) complexes | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/0022-328X(82)80006-5 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/0022-328X(82)80006-5 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |