Chiral micellar electrokinetic chromatography
Identificadores
Enlace permanente (URI): http://hdl.handle.net/10017/47097DOI: 10.1016/j.chroma.2020.461383
ISSN: 00219673
Fecha de publicación
2020-08-30Fecha fin de embargo
2022-08-30Filiación
Universidad de Alcalá. Departamento de Química Analítica Química Física e Ingeniería QuímicaPatrocinadores
Comunidad de Madrid
Ministerio de Ciencia e Innovación
Cita bibliográfica
Journal of Chromatography A, 2020, n. 461383, p. 1-68
Palabras clave
Enantiomeric separations
Micellar Electrokinetic Chromatography
Fundamentals
Chiral separation strategies
analytical applications
Proyectos
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104913GB-I00/ES/ESTRATEGIAS QUIRALES Y METABOLOMICAS NO DIRIGIDAS INNOVADORAS BASADAS EN TECNICAS MICRO-SEPARATIVAS
info:eu-repo/grantAgreement/CAM//S2018%2FBAA-4393/ES/ESTRATEGIAS INTEGRADAS PARA LA MEJORA DE LA CALIDAD, LA SEGURIDAD Y LA FUNCIONALIDAD DE LOS ALIMENTOS: HACIA UNA ALIMENTACIÓN SALUDABLE/AVANSECAL-II-CM
Tipo de documento
info:eu-repo/semantics/article
Versión
info:eu-repo/semantics/publishedVersion
Derechos
Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
© Elsevier
Derechos de acceso
info:eu-repo/semantics/openAccess
Resumen
The potential of Micellar Electrokinetic Chromatography to achieve enantiomeric separations is reviewed in this article. The separation principles and the most frequently employed separation strategies to achieve chiral separations by Micellar Electrokinetic Chromatography are described. The use of chiral micellar systems alone or combined with other micellar systems or chiral selectors, as well as of mixtures of achiral micellar systems with chiral selectors is discussed together with the effect of different additives present in the separation medium. Indirect methods based on the derivatization of analytes with chiral derivatizing reagents and the use of achiral micelles are also considered. Preconcentration techniques employed to improve sensitivity and the main approaches developed to facilitate the coupling with Mass Spectrometry are included. The most recent and relevant methodologies developed by chiral Micellar Electrokinetic Chromatography and their applications in different fields are presented.
Ficheros en el ítem
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Chiral_Salido_JChromA_2020.pdf | 9.602Mb |
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Chiral_Salido_JChromA_2020.pdf | 9.602Mb |
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