| dc.contributor.author | Blom, R. | |
| dc.contributor.author | Rypdal, K. | |
| dc.contributor.author | Mena Montoro, Miguel | |
| dc.contributor.author | Royo Gracia, Pascual | |
| dc.contributor.author | Serrano Roche, Ricardo | |
| dc.date.accessioned | 2009-11-06T09:06:48Z | |
| dc.date.available | 2009-11-06T09:06:48Z | |
| dc.date.issued | 1990 | |
| dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1990, v.391, n.1, p.47-51 | en |
| dc.identifier.issn | 0022-328X | |
| dc.identifier.uri | http://hdl.handle.net/10017/4633 | |
| dc.description.abstract | The thermal average molecular structure of Me3TiCp★ has been determined by gas phase electron diffraction (GED). The GED data are consistent with a molecular model in which the TiMe3 fragment has C3v symmetry and the TiCp★ fragment has C5v symmetry. No static tilt of the methyl groups attached to titanium can be detected, although a flattening of the methyl groups with Ti-C-H 103.8(1.2)° is obtained. The Ti-C(Me) bond distance is 210.7(5) pm, and the Ti-C(Cp★) distance 238.0(5) pm. | en |
| dc.description.sponsorship | Norwegian Research Council for Science and Humanities | en |
| dc.description.sponsorship | VISTA program | en |
| dc.format.mimetype | application/pdf | en |
| dc.language.iso | eng | en |
| dc.publisher | Elsevier | en |
| dc.rights | © Elsevier, 1990 | en |
| dc.subject | Gas phase electron diffraction | en |
| dc.subject | GED | en |
| dc.subject | Methyl groups | en |
| dc.title | The molecular structure of Me3TiCp* in the gas phase | en |
| dc.type | info:eu-repo/semantics/article | en |
| dc.subject.eciencia | Ciencia | es_ES |
| dc.subject.eciencia | Química inorgánica | es_ES |
| dc.subject.eciencia | Science | en |
| dc.subject.eciencia | Chemistry, inorganic | en |
| dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
| dc.relation.publisherversion | http://dx.doi.org/10.1016/0022-328X(90)80155-S | |
| dc.type.version | info:eu-repo/semantics/publishedVersion | en |
| dc.identifier.doi | 10.1016/0022-328X(90)80155-S | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |
