Transition metal complexes with functionalized silyl-substituted cyclopentadienyl and related ligands: synthesis and reactivity
Identificadores
Enlace permanente (URI): http://hdl.handle.net/10017/4213DOI: 10.1016/S0010-8545(99)00139-3
ISSN: 0010-8545
Editor
Elsevier
Fecha de publicación
1999Patrocinadores
Financial support by DGICYT (Project PB97-0776) is gratefully acknowledged.
Cita bibliográfica
Coordination Chemistry Reviews, 1999, v. 193-195, p. 447-498
Palabras clave
Transition metal complexes
Silyl-cyclopentadienyl
Silyl-indenyl
Silyl-fluorenyl
Proyectos
PB97-0776 (Ministerio de Educación y Cultura)
Tipo de documento
info:eu-repo/semantics/article
Versión
info:eu-repo/semantics/publishedVersion
Versión del editor
http://dx.doi.org/10.1016/S0010-8545(99)00139-3Derechos
(c) Elsevier, 1999
Derechos de acceso
info:eu-repo/semantics/openAccess
Resumen
Interest in modifying transition metal complexes using substituted cyclopentadienyl rings has been stimulated in the last years by their potential synthetic and catalytic applications in different processes. This review will feature mono- and dicyclopentadienyl-transition metal complexes containing silyl-cyclopentadienyl and related indenyl and fluorenyl ligands. All of these compounds contain silyl-substituted functionalities which are able to coordinate the metal center or used to introduce such a type of ligating moieties. The synthesis and chemical behaviour of these types of compounds are strongly emphasized. Compounds discussed are all those containing silicon-bound substituents which include: (a) hydrosilyl (Si–H); (b) halosilyl (Si–X); oxosilyl (Si–O); (c) amino– and amido–silyl (Si–N); (d) alkyl– and alkenyl–silyl (Si–C) and (d) boron–silyl (Si–B) compounds. A brief remark on their most significant structural characteristics is also included.
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