dc.contributor.author | Arteaga Müller, Rocío Alejandra | |
dc.contributor.author | Sánchez-Nieves Fernández, Javier | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.contributor.author | González Mosquera, Marta Elena | |
dc.date.accessioned | 2009-10-01T11:40:13Z | |
dc.date.available | 2009-10-01T11:40:13Z | |
dc.date.issued | 2005 | |
dc.identifier.bibliographicCitation | Polyhedron, 2005, v. 24, n. 11, p. 1274-1279 | en |
dc.identifier.issn | 0277-5387 | |
dc.identifier.uri | http://hdl.handle.net/10017/4173 | |
dc.description.abstract | Reactions of the magnesium imides [Mg(NAr)(THF)]6 (Ar = 2,6-Me2C6H3, 1a; Ph, 1b) with [NbCpClCl4] (CpCl = η5-C5H4(SiMe2Cl)) afforded the imido complexes [NbCpClCl2(NAr)] (Ar = 2,6-Me2C6H3, 2a; Ph, 2b) in good yield. Compound 2a reacted with excess LiNH(2,6-Me2C6H3) to give the silyl-η-amido complex [Nb(η5-C5H4SiMe2-η1-NAr)Cl(NAr)] (Ar = 2,6-Me2C6H3, 3a). Hydrolysis of the Si–Cl bond of compounds 2a and 2b yielded the dinuclear complexes [{NbCl2(NAr)}2{(η5-C5H4SiMe2)2(μ-O)}] (Ar = 2,6-Me2C6H3, 4a; Ph, 4b), respectively. All of the new compounds reported were characterized by NMR spectroscopy and the molecular structure of 3a was determined by X-ray diffraction methods. | en |
dc.description.sponsorship | We gratefully acknowledge the Ministerio de Educación y Ciencia (Project MAT2004-02614) and
DGUI-Comunidad de Madrid (Project GR/MAT/0622/2004) (Spain) for financial support. R.A.-M. acknowledges MCyT for a fellowship | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | (C) Elsevier, 2005 | en |
dc.subject | Niobium | en |
dc.subject | Constrained-geometry | en |
dc.subject | Half-sandwich | en |
dc.subject | Imido | en |
dc.subject | Hydrolysis | en |
dc.title | Aryl-imido niobium complexes with chloro-silyl and aryl-η-amidosilyl cyclopentadienyl ligands: X-ray structure of the constrained-geometry compound [Nb(η5-C5H4SiMe2-η1-NAr)(NAr)Cl](Ar=2,6-Me2C6H3) | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.poly.2005.02.027 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/j.poly.2005.02.027 | |
dc.relation.projectID | MAT2004-02614 (Ministerio de Educación y Ciencia) | |
dc.relation.projectID | GR/MAT/0622/2004 (Comunidad de Madrid) | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |