dc.contributor.author | Horno Martín, Estefanía del | |
dc.contributor.author | Jover, Jesús | |
dc.contributor.author | Mena Montoro, Miguel | |
dc.contributor.author | Pérez Redondo, Adrián | |
dc.contributor.author | Yélamos Sánchez, Carlos | |
dc.date.accessioned | 2019-07-04T07:40:29Z | |
dc.date.issued | 2019-05-23 | |
dc.identifier.bibliographicCitation | Chemistry - A European Journal, 2019, v. 25, n. 29, p. 7096-7100 | en |
dc.identifier.issn | 0947-6539 | |
dc.identifier.uri | http://hdl.handle.net/10017/38447 | en |
dc.description.abstract | Titanium(III) complexes containing unprecedented (NH2BH2NHBH3)2‒ and {N(BH3)3}3‒ ligands have been isolated and their structures elucidated by a combination of experimental and theoretical methods. The treatment of the trimethyl derivative [TiCp*Me3] (Cp* = η5-C5Me5) with NH3BH3 (3 equiv) at room temperature gives the paramagnetic dinuclear complex [{TiCp*(NH2BH3)}2(μ-NH2BH2NHBH3)], which at 80 ºC leads to the trinuclear hydride derivative [{TiCp*(μ-H)}3{μ3-N(BH3)3}]. The bonding modes of the anionic BN fragments in those complexes as well as the dimethylaminoborane group trapped on the analogous trinuclear [{TiCp*(μ-H)}3(μ3-H)(μ3-NMe2BH2)] have been studied by X-ray crystallography and density functional theory (DFT) calculations. | en |
dc.description.sponsorship | Ministerio de Economía y Competitividad de España, Universidad de Alcalá | es_ES |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) | en |
dc.rights | © Wiley-VCH Verlag GmbH & Co. KGaA, 2019 | en |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | en |
dc.subject | ammonia-borane | en |
dc.subject | boranes | en |
dc.subject | dehydrogenation | en |
dc.subject | density functional calculations | en |
dc.subject | titanium | en |
dc.title | Ammonia-Borane Derived BN Fragments Trapped on Bi- and Trimetallic Titanium(III) Systems | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Química | es_ES |
dc.subject.eciencia | Chemistry | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica | |
dc.date.updated | 2019-07-04T07:39:30Z | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1002/chem.201900083 | en |
dc.relation.projectID | CTQ2013-33625-R, CTQ2015-64579-C3-1-P, CCGP2017-EXP/021 | en |
dc.date.embargoEndDate | 2020-03-13 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |
dc.identifier.uxxi | AR/0000029978 | en |
dc.identifier.publicationtitle | Chemistry - A European Journal | en |
dc.identifier.publicationvolume | 25 | |
dc.identifier.publicationlastpage | 7100 | |
dc.identifier.publicationissue | 29 | |
dc.identifier.publicationfirstpage | 7096 | |