Enyne ring-closing metathesis on heteroaromatic cations
Authors
Núñez Ventura, Araceli; Cuadro Palacios, Ana María; Álvarez-Builla Gómez, Julio; Vaquero López, Juan J.Identifiers
Permanent link (URI): http://hdl.handle.net/10017/3215DOI: 10.1039/b602420c
ISSN: 1359-7345
Publisher
Royal Society of Chemistry
Date
2006Funders
The authors acknowledge support for this work from the Plan Nacional de Investigación Científica, Desarrollo e Innovación Tecnológica, Ministerio de Ciencia y Tecnología through project BQU2002-03578 and a grant from the Comunidad de Madrid (A. N.).
Ministerio de Ciencia y Tecnología
Bibliographic citation
Chemical Communications, 2006, n. 25, p. 2690-2692
Keywords
1 Vinyl 3,4 dihydroquinolizinium derivative
2 Vinyl 3,4 dihydroquinolizinium derivative
Berberine derivative
Cation
Coralyne
Dihydroquinoline derivative
Enyne derivative
Ethylene
Heteroaromatic cation
Unclassified drug
Article
Cation transport
Chemical structure
Product recovery
Ring closing metathesis
Structure activity relation
Structure analysis
Project
info:eu-repo/grantAgreement/MICYT//BQU2002-03578/ES/NUEVOS CROMOFOROS CON PROPIEDADES INTERCALANTES DE ADN, AFINIDAD Y SELECTIVIDAD
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1039/b602420cRights
(C) The Royal Society of Chemistry, 2006
Access rights
info:eu-repo/semantics/openAccess
Abstract
Cationic heteroaromatic enynes have been employed as substrates in enyne ring-closing metathesis, under an atmosphere of ethylene and using the Hoveyda-Grubbs catalyst, for the first time; the reaction affords new 1-vinyl- and 2-vinyl-substituted 3,4-dihydroquinolizinium salts, useful precursors for biologically relevant cations based on the quinolinizium system.
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