%0 Journal Article 
%A Abengózar Muñoz, Alberto
%A Fernández González, Miguel Ángel
%A Sucunza Sáenz, David
%A Frutos Gaite, Luis Manuel
%A Salgado Serrano, Antonio
%A García García, Patricia
%A Vaquero López, Juan J.
%T C−H Functionalization of BN-Aromatics Promoted by Addition of Organolithium Compounds to the Boron Atom
%D 2018
%@ 1523-7060
%U http://hdl.handle.net/10017/43801
%X Addition of an organolithium compound to a BN-phenanthrene with embedded B and N atoms is proposed to result in coordination of RLi to the boron atom. This coordination, supported by NMR spectroscopy and DFT calculations, increases the nucleophilicity of the system in the b position to the N atom, and is therefore a useful tool for promoting regioselective C-H functionalization of BN aromatics
%K BN-phenanthrene
%K C-H functionalization
%K organolithium compound
%K NMR
%K DFT
%K Química
%K Chemistry
%~ Biblioteca Universidad de Alcala