RT info:eu-repo/semantics/article T1 Reactions of complexes of gold(I) with bis(pentafluorophenyl)thallium(III) halides A1 Usón Lacal, R. A1 Royo Gracia, Pascual A1 Laguna, A. K1 Gold(I) K1 Bis(pentafluorophenyl)thallium(III) halides K1 Ciencia K1 Química inorgánica K1 Science K1 Chemistry, inorganic AB The reactions of bis(pentafluorophenyl)thallium(III) halides with XAuL (L = PPh3, AsPh3) lead to results which vary according to the character of X. When X is Cl, Br or I an oxidation from gold(I) to gold(III) takes place through the transference of two C6F5 groups, and with the simultaneous precipitation of thallous halide.When X is C6F5, C6H5, NO3, CH3COO, SCN or PPh3 substitution but not oxidation takes place, which may be followed by secondary reactions.Reasons for this behaviour are discussed. PB Elsevier SN 0022-328X YR 1974 FD 1974 LK http://hdl.handle.net/10017/4939 UL http://hdl.handle.net/10017/4939 LA eng DS MINDS@UW RD 29-mar-2024