RT info:eu-repo/semantics/article
T1 Pentafluorophenyl complexes of cobalt(III) with 1-(diacetylmonoximatoimino)-3-(diacetylmonoximeimino)-propane (dotnH)
A1 Royo Gracia, Pascual
A1 Sancho Royo, José
K1 Cobalt(III)
K1 Ciencia
K1 Química inorgánica
K1 Science
K1 Chemistry, inorganic
AB The treatment of Br2Co(dotnH) with the C6F5MgBr Grignard reagent leads to the isolation of (C6F5)BrCo(dotnH). Substitution reactions of this substances make it possible to isolate neutral complexes ((C6F5)CoX(dotnH) (X = CN-, SCN- I-, NO2-)), mononuclear cationic complexes ([C6F5)Co(dotnH)L]Y (L = H2O, NH3, py; Y = ClO4-, BPh4-) and binuclear cationic complexes ({(C6F5)Co-(dotnH)]2X} +BPh4-(X = CN-,SCN-)).The new complexes were studied by IR, visible-UV and NMR spectroscopy.
PB Elsevier
SN 0022-328X
YR 1977
FD 1977
LK http://hdl.handle.net/10017/4934
UL http://hdl.handle.net/10017/4934
LA eng
NO Ministerio de Educación y Ciencia
DS MINDS@UW
RD 25-abr-2024