RT info:eu-repo/semantics/article T1 Neutral and cationic pentafluorophenylnickel(II) complexes A1 Caballero, F. A1 Royo Gracia, Pascual K1 Pentafluorophenylnickel(II) complexes K1 Ciencia K1 Química inorgánica K1 Science K1 Chemistry, inorganic AB Metathetical reactions of Br(C6F5)Ni(PPh3)2 with metal salts MX (NaI, NaNO2, NaNO3, KCN, KSCN, AgClO4) have given the corresponding X(C6F5)Ni(PPh3)2 complexes. The perchlorate group of the complex (O3ClO)Ni(C6F5)(PPh3)2 is readily displaced. In this way cationic complexes [(C6F5)Ni(PPh3)2L]ClO4 have been prepared with L --- PPh3, PEt3, P-t-Bu3, AsPh3, C5H5N, OPPh3, SPPh3, H2O, or CH3NO2. PB Elsevier SN 0022-328X YR 1977 FD 1977 LK http://hdl.handle.net/10017/4891 UL http://hdl.handle.net/10017/4891 LA eng NO We greatly appreciate financial support from Comisión Asesora de Investiga­ción Cientifica y Tecnica (Spain). DS MINDS@UW RD 28-mar-2024