RT info:eu-repo/semantics/article
T1 Phenoxotantalum(V) complexes
A1 Gómez Rubio, Manuel
A1 Royo Gracia, Pascual
A1 Selas Pérez, José Manuel
K1 Phenoxotantalum(V)
K1 Ciencia
K1 Química inorgánica
K1 Science
K1 Chemistry, inorganic
AB The reaction of the compounds TaXCl4 (X = η5-C5H5, η5-C5H4SiMe3 or Cl) with o-diphenols 4-RC6H3(OH)2 (R = H, Me, But gave the dialkoxides XCl2Ta(O2C6H3R), whereas the reaction with 4,4′-isopropylidenediphenol gave the monoalkoxides [TaXCl3]2[(OC6H4)2CMe2]. Osmometry shows the cyclopentadienyl derivatives with X = η-C5H4SiMe3 and R = Me, But to be dimeric in benzene, but the halogeno complex with X = Cl and R = But to be trimeric. The new alkoxide complexes have been characterised by IR and 1H and 13C NMR spectroscopy.
PB Elsevier
SN 0022-328X
YR 1986
FD 1986
LK http://hdl.handle.net/10017/4789
UL http://hdl.handle.net/10017/4789
LA eng
DS MINDS@UW
RD 20-abr-2024