RT info:eu-repo/semantics/article
T1 Halo(alkoxo) and monocyclopentadienyl(halo)alkoxo derivatives of titanium, zirconium and hafnium
A1 Gómez Carrera, José Alberto
A1 Mena Montoro, Miguel
A1 Royo Gracia, Pascual
A1 Serrano Roche, Ricardo
K1 Olefins
K1 Zirconium derivatives
K1 Ciencia
K1 Química inorgánica
K1 Science
K1 Chemistry, inorganic
AB The chlorides MCl4 (M = Ti, Zr, Hf) react with the diols 4,4′-Me2C(C6H4OH)2 and 1,2-(OH)2Ar, Ar = C6H4, 4-MeC6H3, or 4-ButC6H3 to give the halogenoalkoxo derivatives MCl2(O2Ar). For M  Ti these react with bases L (L = 2,2′-bipy, THF, Et2O) to give the corresponding adducts TiCl2(O2Ar)L, and with TlCp to give the monocyclopentadienyl complexes CpTiCl(O2Ar). The best way of preparing the analogous zirconium derivatives is through the reaction of CpZrCl3 · DME with (HO)2Ar.
PB Elsevier
SN 0022-328X
YR 1986
FD 1986
LK http://hdl.handle.net/10017/4788
UL http://hdl.handle.net/10017/4788
LA eng
DS MINDS@UW
RD 25-abr-2024