RT info:eu-repo/semantics/article
T1 New neutral and cationic cyclopentadienylcobalt complexes
A1 Avilés, T.
A1 Barroso Parla, Francisca
A1 Royo Gracia, Pascual
K1 Cyclopentadienylcobalt complexes
K1 Ciencia
K1 Química inorgánica
K1 Science
K1 Chemistry, inorganic
AB The treatment of the aquocation [Co(η3-2-MeC3H4)(η5-C5H5)(H2O]+ with neutral and anionic ligands gives new cobalt complexes containing cations [Co(η3-2-MeC3H4)(η5-C5H5)L]n+, n = 0; L = CN, CH3COO, CF3COO and n = 1; L = P(p-MePh)3, NCEt, NCPh, CNCy, dppm and [{Co(η3-2-MeC3H4)(η5-C5H5)}2 (μ-L-L)]2+, L-L = bipy, dppm. The neutral cyano complex reacts with various electrophiles to give cationic isocyanide complexes containing the cation [Co(η3-2-MeC3H4)(η5-C5H5)(CNR)]+, which have been isolated in low yields. Chemical behaviour and structural implications of IR and 1H and 13C NMR spectra are discussed.
PB Elsevier
SN 0022-328X
YR 1987
FD 1987
LK http://hdl.handle.net/10017/4664
UL http://hdl.handle.net/10017/4664
LA eng
NO The authors greatly appreciate financial support from the Comisión Asesora de Investigación Científica y Técnica. Ref. 2001/83. Spain.
DS MINDS@UW
RD 25-abr-2024