RT info:eu-repo/semantics/article T1 C−H Functionalization of BN-Aromatics Promoted by Addition of Organolithium Compounds to the Boron Atom A1 Abengózar Muñoz, Alberto A1 Fernández González, Miguel Ángel A1 Sucunza Sáenz, David A1 Frutos Gaite, Luis Manuel A1 Salgado Serrano, Antonio A1 García García, Patricia A1 Vaquero López, Juan J. K1 BN-phenanthrene K1 C-H functionalization K1 organolithium compound K1 NMR K1 DFT K1 Química K1 Chemistry AB Addition of an organolithium compound to a BN-phenanthrene with embedded B and N atoms is proposed to result in coordination of RLi to the boron atom. This coordination, supported by NMR spectroscopy and DFT calculations, increases the nucleophilicity of the system in the b position to the N atom, and is therefore a useful tool for promoting regioselective C-H functionalization of BN aromatics SN 1523-7060 YR 2018 FD 2018-08-17 LK http://hdl.handle.net/10017/43801 UL http://hdl.handle.net/10017/43801 LA eng DS MINDS@UW RD 28-mar-2024