RT info:eu-repo/semantics/article
T1 Practical solvent-free microwave-assisted hydroboration of alkynes
A1 Altarejos Salido, Julia
A1 Sucunza Sáenz, David
A1 Vaquero López, Juan J.
A1 Carreras Pérez Aradros, Javier
K1 Alkynes
K1 Hydroboration
K1 Microwave chemistry
K1 Alkenyl boronates
K1 Solvent-free synthesis
K1 Química
K1 Chemistry
AB A simple and rapid protocol for the anti-Markovnikov hydroboration of alkynes assisted by microwave irradiation has been developed. Pinacolborane smoothly reacts with terminal alkynes to obtain (E)-alkenyl boronates in good yields and short reactions times in the absence of solvent. Further transformations on the carbon-boron bond of the adducts can be sequentially achieved without the need of purifying the alkenyl boronates.
SN 1434-193X
YR 2020
FD 2020-04-16
LK http://hdl.handle.net/10017/43407
UL http://hdl.handle.net/10017/43407
LA eng
DS MINDS@UW
RD 18-abr-2024