RT info:eu-repo/semantics/article
T1 Synthesis of chloro and methyl imido cyclopentadienyl molybdenum and tungsten complexes. X-ray molecular structures of [WCp*C13(NtBu)], [MoCp*C1Me2(NtBu) ] and [WCp*C1Me2(NtBu) ]
A1 Gómez Sal, Pilar
A1 Jiménez Sanz, Ignacio
A1 Martín Alonso, Avelino
A1 Pedraz Gallego, Teresa
A1 Royo Gracia, Pascual
A1 Sellés Peñaranda, Alberto
A1 Vázquez de Miguel, Amelio
K1 Molybdenum complexes
K1 Tungsten complexes
K1 Imido complexes
K1 AIkyl complexes
K1 Cyclopentadienyl complexes
K1 Crystal structures
K1 Ciencia
K1 Química inorgánica
K1 Science
K1 Chemistry, inorganic
AB Alternative methods to prepare [MCp'C14], [MCp'CL(N'Bu)] and [MCp'CI~(N'Bu)] [M=Mo, Cp'="qs-C~Me~ (Cp*); M=W,Cp' = r/5-CsH5 (Cp), r/5-CsMe5 (Cp*) ] in high yields are reported. Alkylation of [MCp'CI3(N'Bu) ] with stoichiometric amounts of LiMeor MeMgC1 under appropriate conditions leads to the dimethyl [MCp'CIMe2(N'Bu)] and trimethyl [MCp'Me~(N'Bu)], (M=Mo,Cp' = Cp*; M = W, Cp' = Cp, Cp* ) complexes. The 18-electron trimethyltungsten complex [WCp*Me~(N'Bu) ] reacts very slowly withCN(2,6-Me2C~,H3) to give the insertion product [WCp*{C(Me)= N(2,6-Me2C6H3)}Me2(N'Bu)]. All of the new compounds reportedwere characterized by elemental analyses, IR and NMR spectroscopy and the X-ray molecular structures of [WCp*CI~(N'Bu)],[ MoCp*CIMe2( N'Bu ) ] and [ WCp*C1Me_,.(NtBu ) ] have been determined by diffraction methods. O 1998 Elsevier Science S.A. All rightsreserved.
PB Elsevier
SN 0020-1693
YR 1998
FD 1998
LK http://hdl.handle.net/10017/4278
UL http://hdl.handle.net/10017/4278
LA eng
NO The authors acknowledge DGICYT (Project PB92-0178-C) and CAM (I + D 0033/94) for financial support.
DS MINDS@UW
RD 25-abr-2024