RT info:eu-repo/semantics/article
T1 Alkyl and alkylidene imido cyclopentadienyl tungsten complexes
A1 Acebrón Moreno, Sergio
A1 Galakhov, Mikhail V.
A1 Gómez Sal, Pilar
A1 Martín Alonso, Avelino
A1 Royo Gracia, Pascual
A1 Vázquez de Miguel, Amelio
K1 Alkyl
K1 Alkylidene
K1 Imido
K1 Tungsten
K1 Ciencia
K1 Química inorgánica
K1 Science
K1 Chemistry, inorganic
AB This paper reports the alkylation of the cyclopentadienyl imido tungsten complexes [WCp′(NtBu)Cl3] (Cp′=η5-C5H5, η5-C5Me5) with β-hydrogen containing alkyl groups to render halo alkyl and trialkyl complexes [WCp′(NtBu)Cl3−nRn] (R=Et, n-Pr). Thermal decomposition of the trialkyl compounds gives the alkylidene derivatives [WCp′(NtBu)(CHR)(CH2R)] (R=Me, Et) by α-hydrogen elimination. All of the compounds were characterized by NMR spectroscopy and the molecular structure of [W(η5-C5Me5)(NtBu)Et3] was determined by X-ray diffraction methods.
PB Elsevier
SN 0022-328X
YR 1999
FD 1999
LK http://hdl.handle.net/10017/4243
UL http://hdl.handle.net/10017/4243
LA eng
NO The authors acknowledge DGICYT (project PB97-0677) for financial support.
DS MINDS@UW
RD 27-abr-2024