RT info:eu-repo/semantics/article
T1 Transition metal complexes with functionalized silyl-substituted cyclopentadienyl and related ligands: synthesis and reactivity
A1 Cuenca Agreda, José Tomás
A1 Royo Gracia, Pascual
K1 Transition metal complexes
K1 Silyl-cyclopentadienyl
K1 Silyl-indenyl
K1 Silyl-fluorenyl
K1 Ciencia
K1 Química inorgánica
K1 Science
K1 Chemistry, inorganic
AB Interest in modifying transition metal complexes using substituted cyclopentadienyl rings has been stimulated in the last years by their potential synthetic and catalytic applications in different processes. This review will feature mono- and dicyclopentadienyl-transition metal complexes containing silyl-cyclopentadienyl and related indenyl and fluorenyl ligands. All of these compounds contain silyl-substituted functionalities which are able to coordinate the metal center or used to introduce such a type of ligating moieties. The synthesis and chemical behaviour of these types of compounds are strongly emphasized. Compounds discussed are all those containing silicon-bound substituents which include: (a) hydrosilyl (Si–H); (b) halosilyl (Si–X); oxosilyl (Si–O); (c) amino– and amido–silyl (Si–N); (d) alkyl– and alkenyl–silyl (Si–C) and (d) boron–silyl (Si–B) compounds. A brief remark on their most significant structural characteristics is also included.
PB Elsevier
SN 0010-8545
YR 1999
FD 1999
LK http://hdl.handle.net/10017/4213
UL http://hdl.handle.net/10017/4213
LA eng
NO Financial support by DGICYT (Project PB97-0776) is gratefully acknowledged.
DS MINDS@UW
RD 24-abr-2024