RT info:eu-repo/semantics/article
T1 Reactivity of vinyl and alkynyl zirconium complexes with the di-ansa-[1,1′,2,2′-bis(dimethylsilanediyl) dicyclopentadienyl] ligand
A1 Fernández Álvarez, Francisco José
A1 Galakhov, Mikhail V.
A1 Royo Gracia, Pascual
K1 Zirconium
K1 Alkenyl
K1 Alkyny
K1 Alkylzirconacycles
K1 Ciencia
K1 Química inorgánica
K1 Science
K1 Chemistry, inorganic
AB Vinylation of the chloro–ethyl and dichloro zirconium complexes [Zr(CpSi2Cp)ClX] (CpSi2Cp=1,1′,2,2′-(SiMe2)2(η5-C5H3)2; X=Et, Cl) with one or two equivalents of Mg(CH=CH2)Cl gave the new zirconacyclopentane [Zr(CpSi2Cp){η2-CH2-(CH2)2-CH2}] and (η4-butadiene)zirconium [Zr(CpSi2Cp){η4-(butadiene)}] complexes, respectively. Addition of a toluene solution of PhC=CPh to the zirconacyclopentane compound afforded the zirconacyclopentadiene derivative [Zr(CpSi2Cp){η2-(CPh=CPh-CPh=CPh)}]. Reaction of the chloro–ethyl zirconium complex with LiC=CPh afforded the alkynyl compound [Zr(CpSi2Cp)Et(C=CPh)] which reacted with CN(2,6-Me2C6H3) to give the insertion product [Zr(CpSi2Cp)(C=CPh){η2-C(Et)=N(2,6-Me2C6H3)}]. Reactions of the chloro–ethyl [Zr(CpSi2Cp)EtCl] and alkynyl-ethyl [Zr(CpSi2Cp)Et(C=CPh)] complexes with the Lewis acid B(C6F5)3 yielding various cationic species have been monitored by 1H-NMR spectroscopy. The new complexes reported and their intermediates have been identified by IR and 1H- and 13C-NMR spectroscopy.
PB Elsevier
SN 0022-328X
YR 2000
FD 2000
LK http://hdl.handle.net/10017/4212
UL http://hdl.handle.net/10017/4212
LA eng
DS MINDS@UW
RD 25-abr-2024