RT info:eu-repo/semantics/article
T1 Synthesis and reactivity of di(silylamido)cyclopentadienyl titanium and zirconium complexes
A1 Cano Sierra, Jesús
A1 Sudupe Ormeño, María
A1 Royo Gracia, Pascual
K1 Silylamido
K1 Cyclopentadienyl
K1 Titanium
K1 Zirconium
K1 Ciencia
K1 Química inorgánica
K1 Science
K1 Chemistry, inorganic
AB We present in this account the synthesis and recent developments of a new class of group 4 metal complexes with the tridentate di(silylamido)cyclopentadienyl ligand. These doubly silyl-bridged group 4 metal amido chelates are receiving increasing interest as they are efficient catalysts for ethene polymerization when activated with MAO despite generating 14-electron d0 cationic species free of the alkyl group required for the first insertion reaction in the polymerization process.
PB Elsevier
SN 0022-328X
YR 2007
FD 2007
LK http://hdl.handle.net/10017/4170
UL http://hdl.handle.net/10017/4170
LA eng
NO Programa Juan de la Cierva (Ministerio de Educación y Ciencia)
DS MINDS@UW
RD 23-abr-2024