RT info:eu-repo/semantics/article T1 Isolable zirconium hydride species in the reaction of amido complexes with amine-boranes A1 Greño Ocariz, Maider A1 Mena Montoro, Miguel A1 Pérez Redondo, Adrián A1 Yélamos Sánchez, Carlos K1 Química K1 Chemistry AB Mono-, di- and trinuclear zirconium hydride species have been isolated in the treatment of amido complexes [Zr(η5-C5Me5)(NMe2)nCl3-n] (n = 3, 1) with amine‒borane adducts NHR2BH3 (R2 = Me2, HtBu). The reactions involve the formation of amidoborane ligands with Zr···H-B interactions which readily undergo β-hydride elimination to give hydride functions. SN 1477-9226 YR 2017 FD 2017-04-28 LK http://hdl.handle.net/10017/38446 UL http://hdl.handle.net/10017/38446 LA eng NO Ministerio de Economía y Competitividad de España, Universidad de Alcalá DS MINDS@UW RD 29-mar-2024