RT info:eu-repo/semantics/article
T1 Revisiting the synthesis of trans-[Pt(dmso)2ClMe] and cis-[Pt(dmso)2Me2]: Experimental and DFT studies
A1 Baquero Velasco, Edwin Arley
A1 Rodriguez Zuñiga, Ana
A1 Flores Serrano, Juan C.
A1 Temprado Morena, Manuel
A1 Jesús Alcañiz, Ernesto de
K1 Platinum
K1 Alkyl complexes
K1 Synthesis
K1 DFT calculations
K1 Química
K1 Chemistry
AB The preparation of trans-[Pt(dmso)2ClMe] (2) and cis-[Pt(dmso)2Me2] (3) from cis-[Pt(dmso)2Cl2] (1) and SnMe4has been reexamined (dmso = dimethyl sulfoxide). The information obtained from experimental and DFT studies has permitted the improvement of previously reported methods for the synthesis of both complexes in terms of reaction times, reaction yields, and atom economy. These studies show that complex 1reacts with a first equiv of SnMe4to form trans-[Pt(dmso)2ClMe] (2) as an intermediate that quickly reacts with a second equiv of SnMe4to yield cis-[Pt(dmso)2Me2] (3). When only 1 equiv of the organostannane reagent is added, the comproportionation of 3with the excess of unreacted 1leads the reaction back to the formation of trans-[Pt(dmso)2ClMe] (2). The mechanism of this comproportionation has been studied using DFT calculations.
SN 0022-328X
YR 2019
FD 2019-06-07
LK http://hdl.handle.net/10017/38268
UL http://hdl.handle.net/10017/38268
LA eng
NO Ministerio de Ciencia, Innovación y Universidades
DS MINDS@UW
RD 26-abr-2024