RT info:eu-repo/semantics/article T1 Azinium-N-(2'-azinyl)aminides: synthesis, structure and reactivity A1 Carceller Martí, Rosa A1 García Navío, José Luis A1 Izquierdo Ceinos, Ma Luisa A1 Álvarez-Builla Gómez, Julio A1 Fajardo, Mariano A1 Gómez Sal, Pilar A1 Gago Badenas, Federico K1 Salts K1 Betaines K1 Ylides K1 Ciencia K1 Química orgánica K1 Science K1 Chemistry, organic AB Several azinium-N-(2'-azinyl)aminides are reported. The structure of pyridinium-N-(2'-pyridyl)aminide has been studied, both in solution and in crystalline state, and results have been compared. In non-polar solvents, the aminides present a planar conformation stabilized by an intramolecular hydrogen bond. The reactivity toward electrophiles confirms the structural data, producing either N- or C- substitutions under mild conditions. PB Pergamon SN 0040-4020 YR 1994 FD 1994 LK http://hdl.handle.net/10017/3669 UL http://hdl.handle.net/10017/3669 LA eng DS MINDS@UW RD 29-mar-2024