RT info:eu-repo/semantics/article
T1 Synthesis of aldehydes from acyl chlorides via 1-(acylmethylamino)-3-methylimidazolium salts
A1 Heras Muñoz, María Amor de las
A1 Vaquero López, Juan J.
A1 García Navío, José Luis
A1 Álvarez-Builla Gómez, Julio
K1 Palladium-catalyzed reaction
K1 Tributylin hydride
K1 Carboxylic-acids
K1 Reduction
K1 Tetrahydroborate
K1 Route
K1 Chemistry, Organic
K1 Ciencia
K1 Química orgánica
K1 Science
K1 Chemistry, organic
AB The reaction of acyl chlorides with 1-amino-3-methylimidazolium salts, followed by N-methylation of the resulting H-aminides, afforded 1-(acylmethylamino)-3-methylimidazolium salts which, upon treatment with DIBALHgave aldehydes in good yields. A nalogously, dialdehydes were obtained from the corresponding bis-salts.
PB Pergamon
SN 0040-4039
YR 1995
FD 1995
LK http://hdl.handle.net/10017/2790
UL http://hdl.handle.net/10017/2790
LA eng
NO The authors are grateful for grant (MAH) from Ministerio de Educación y Cienciaand financial support from Comisión Interministerial de Ciencia y Tecnología (CICYT) through the projectPB90-0284
DS MINDS@UW
RD 20-abr-2024