RT info:eu-repo/semantics/article T1 Chemoselective addition of grignard reagents to alkoxycarbonylalkyl-N-imidazolium-N-methyl amides: synthesis of 4-oxo and homologous esters A1 Heras Muñoz, María Amor de las A1 Vaquero López, Juan J. A1 García Navío, José Luis A1 Álvarez-Builla Gómez, Julio K1 Addition reaction K1 Grignard reagents role: RCT K1 Amides role K1 Chemoselective addn K1 Carboxylic acids role K1 Chemoselective K1 ADDN K1 Grignard K1 Imidazoliomethyl K1 Amide K1 Oxo K1 Ester K1 Bioquímica K1 Biochemistry K1 Science K1 Ciencia AB A method for the synthesis of 4-oxo and homologous esters is achieved by metalation of alkoxycarbonylalkyl-N-imidazolium-N-methyl amides with 1equiv of LDA followed by highly chemoselective addition of 1 equiv of a Grignard reagent. PB Pergamon SN 0040-4039 YR 1997 FD 1997 LK http://hdl.handle.net/10017/2707 UL http://hdl.handle.net/10017/2707 LA eng NO Ministerio de Educación y Ciencia DS MINDS@UW RD 25-abr-2024