RT info:eu-repo/semantics/article
T1 Spectrophotometric determination of copper(II), nickel(II), and cobalt(II) as complexes with sodium diethyldithiocarbamate in the anionic micellar media of dodecylsulfate salts
A1 San Andrés Lledó, María Paz
A1 Marina Alegre, María Luisa
A1 Vera López, María Soledad
K1 Micelles
K1 Spectrophotometry
K1 Metal ions
K1 Diethyldithiocarbamate
K1 Ciencia
K1 Química
K1 Science
K1 Chemistry
AB Copper(II), NiII and CoII were determined spectrophotometrically as their complexes with diethyldithiocarbamate (DDTC) in the presence of aqueous anionic micellar media of sodium and ammonium dodecylsulfate. The presence of micellar systems allows one to eliminate the previous solvent extraction step that is necessary for the determination of metal–DDTC complexes in the absence of micelles. This reduces the cost and toxicity of the method. The influence of anionic micelles on the analytical characteristics (sensitivity and detection limits) was studied. The proposed method was applied to the determination of CuII in industrial waste water and in nickel covered metallic samples, and the results were compared with those obtained by flame atomic absorption spectrometry.
PB Royal Society of Chemistry
SN 0003-2654
YR 1995
FD 1995
LK http://hdl.handle.net/10017/21120
UL http://hdl.handle.net/10017/21120
LA eng
NO Received January 17, 1994; Accepted April 18, 1994
DS MINDS@UW
RD 09-dic-2023