1,10a-Dihydro-1-aza-10a-boraphenanthrene and 6a,7-Dihydro-7-aza-6a-boratetraphene: Two New Fluorescent BN-PAHs

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Authors
Valencia Nieto, IsabelUniversity of Alcalá Author; García García, PatriciaUniversity of Alcalá Author; Sucunza Sáenz, DavidUniversity of Alcalá Author; Mendicuti Madrid, Francisco Enrique JavierUniversity of Alcalá Author; Vaquero López, Juan JoséUniversity of Alcalá Author
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/59152
DOI: 10.1021/acs.joc.1c01095
ISSN: 0022-3263
Date
2021-11-17
Academic Departments
Universidad de Alcalá. Departamento de Química Analítica, Química Física e Ingeniería Química
Universidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica
Teaching unit
Unidad docente Química Orgánica
Funders
Ministerio de Ciencia e Innovación
University of Alcalá
Instituto de Salud Carlos III
Bibliographic citation
The Journal of Organic Chemistry, 2021, v. 86, n. 23, p. 16259-16267
Project
info:eu-repo/grantAgreement/MICINN//CTQ2017-85263-R/ES/
info:eu-repo/grantAgreement/UAH//CCG19%2FCC-017/ES/
info:eu-repo/grantAgreement/UAH//CCG19%2FCC-033/ES/
info:eu-repo/grantAgreement/ISCIII//RETICREDINREN RD16%2F0009%2F0015/ES/
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Rights
© The Authors
Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
Access rights
info:eu-repo/semantics/openAccess
Abstract
Previously unknown 1,10a-dihydro-1-aza-10a-boraphenanthreneand 6a,7-dihydro-7-aza-6a-boratetraphene have been efficiently synthesized.Bromination of these BN-PAHs proceeds with complete regioselectivity, resultingin the formation of different substituted derivatives via cross-coupling reactions.These compounds exhibit rather highfluorescence quantum yields (up to?F=0.80)

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