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N=N Bond Cleavage by Tantalum Hydride Complexes: Mechanistic Insights and Reactivity.

dc.contributor.authorÁlvarez Ruiz, Elena 
dc.contributor.authorCarbó, Jorge J.
dc.contributor.authorGómez Rubio, Manuel 
dc.contributor.authorHernández Prieto, Cristina 
dc.contributor.authorHernán-Gómez Robledo, Alberto 
dc.contributor.authorMartín Alonso, Avelino 
dc.contributor.authorMena Montoro, Miguel 
dc.contributor.authorRicart, Josep M.
dc.contributor.authorSalom Catalá, Antoni
dc.contributor.authorSantamaría Angulo, Cristina 
dc.date.accessioned2022-01-17T07:37:42Z
dc.date.available2022-01-17T07:37:42Z
dc.date.issued2022-01-10
dc.identifier.bibliographicCitationInorganic Chemistry, 2022, v. 61, n. 1, p. 474-485en
dc.identifier.issn0020-1669
dc.identifier.urihttp://hdl.handle.net/10017/50368en
dc.description.abstractA series of dinuclear tantalum(IV) hydrides [{TaCpRX2}2(mu-H)2] (CpR = eta5-C5Me5, eta5-C5H4SiMe3, eta5-C5HMe4; X = Cl, Br) show the ability to promote the N=N bond cleavage in their reactions with azobenzene and benzo[c]cinnoline in absence of reducing reagents. Both, characterization of intermediate species and DFT studies point to a mechanism in two stages, in which the Ta-Ta bond splitting is key for the reduction of the N=N bond and its complete scission.en
dc.description.sponsorshipConsorcio Madroño - Universidad de Alcalaes_ES
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)en
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.titleN=N Bond Cleavage by Tantalum Hydride Complexes: Mechanistic Insights and Reactivity.en
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaQuímicaes_ES
dc.subject.ecienciaChemistryen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Orgánica y Química Inorgánicaes_ES
dc.date.updated2022-01-17T07:37:13Z
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1021/acs.inorgchem.1c03152en
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-094007-B-I00/ES/SISTEMAS MOLECULARES MULTIMETALICOS PARA LA ACTIVACION Y FUNCIONALIZACION DE DINITROGENO/es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen
dc.identifier.uxxiAR/0000038339en
dc.identifier.publicationtitleInorganic Chemistryen
dc.identifier.publicationvolume61
dc.identifier.publicationlastpage485
dc.identifier.publicationissue1
dc.identifier.publicationfirstpage474


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