| dc.contributor.author | Usón Lacal, R. | |
| dc.contributor.author | Royo Gracia, Pascual | |
| dc.contributor.author | Laguna, A. | |
| dc.date.accessioned | 2009-11-18T14:11:10Z | |
| dc.date.available | 2009-11-18T14:11:10Z | |
| dc.date.issued | 1974 | |
| dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1974, v. 69, n. 3, p. 361-365 | en |
| dc.identifier.issn | 0022-328X | |
| dc.identifier.uri | http://hdl.handle.net/10017/4939 | |
| dc.description.abstract | The reactions of bis(pentafluorophenyl)thallium(III) halides with XAuL (L = PPh3, AsPh3) lead to results which vary according to the character of X. When X is Cl, Br or I an oxidation from gold(I) to gold(III) takes place through the transference of two C6F5 groups, and with the simultaneous precipitation of thallous halide.
When X is C6F5, C6H5, NO3, CH3COO, SCN or PPh3 substitution but not oxidation takes place, which may be followed by secondary reactions.
Reasons for this behaviour are discussed. | en |
| dc.format.mimetype | application/pdf | en |
| dc.language.iso | eng | en |
| dc.publisher | Elsevier | en |
| dc.rights | (c) Elsevier, 1974 | en |
| dc.subject | Gold(I) | en |
| dc.subject | Bis(pentafluorophenyl)thallium(III) halides | en |
| dc.title | Reactions of complexes of gold(I) with bis(pentafluorophenyl)thallium(III) halides | en |
| dc.type | info:eu-repo/semantics/article | en |
| dc.subject.eciencia | Ciencia | es_ES |
| dc.subject.eciencia | Química inorgánica | es_ES |
| dc.subject.eciencia | Science | en |
| dc.subject.eciencia | Chemistry, inorganic | en |
| dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
| dc.relation.publisherversion | http://dx.doi.org/10.1016/S0022-328X(00)89739-9 | |
| dc.type.version | info:eu-repo/semantics/publishedVersion | en |
| dc.identifier.doi | 10.1016/S0022-328X(00)89739-9 | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |
