Reactions of complexes of gold(I) with bis(pentafluorophenyl)thallium(III) halides

Authors
Usón Lacal, R.; Royo Gracia, PascualUniversity of Alcalá Author; Laguna, A.
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4939
DOI: 10.1016/S0022-328X(00)89739-9
ISSN: 0022-328X
Publisher
Elsevier
Date
1974
Affiliation
Universidad de Alcalá. Departamento de Química Inorgánica
Bibliographic citation
Journal of Organometallic Chemistry, 1974, v. 69, n. 3, p. 361-365
Keywords
Gold(I)
Bis(pentafluorophenyl)thallium(III) halides
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/S0022-328X(00)89739-9
Rights
(c) Elsevier, 1974
Access rights
info:eu-repo/semantics/openAccess
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Abstract
The reactions of bis(pentafluorophenyl)thallium(III) halides with XAuL (L = PPh3, AsPh3) lead to results which vary according to the character of X. When X is Cl, Br or I an oxidation from gold(I) to gold(III) takes place through the transference of two C6F5 groups, and with the simultaneous precipitation of thallous halide. When X is C6F5, C6H5, NO3, CH3COO, SCN or PPh3 substitution but not oxidation takes place, which may be followed by secondary reactions. Reasons for this behaviour are discussed.
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