Reactions of complexes of gold(I) with bis(pentafluorophenyl)thallium(III) halides

  View metrics of use
Utilizar EndNote Import
Authors
Usón Lacal, R.; Royo Gracia, PascualUniversity of Alcalá Author; Laguna, A.
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4939
DOI: 10.1016/S0022-328X(00)89739-9
ISSN: 0022-328X
Publisher
Elsevier
Date
1974
Academic Departments
Universidad de Alcalá. Departamento de Química Inorgánica
Teaching unit
Unidad docente Química Inorgánica
Bibliographic citation
Journal of Organometallic Chemistry, 1974, v. 69, n. 3, p. 361-365
Keywords
Gold(I)
Bis(pentafluorophenyl)thallium(III) halides
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/S0022-328X(00)89739-9
Rights
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Access rights
info:eu-repo/semantics/openAccess
Abstract
The reactions of bis(pentafluorophenyl)thallium(III) halides with XAuL (L = PPh3, AsPh3) lead to results which vary according to the character of X. When X is Cl, Br or I an oxidation from gold(I) to gold(III) takes place through the transference of two C6F5 groups, and with the simultaneous precipitation of thallous halide. When X is C6F5, C6H5, NO3, CH3COO, SCN or PPh3 substitution but not oxidation takes place, which may be followed by secondary reactions. Reasons for this behaviour are discussed.

Show full item record

Files in this item
Collections
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Este ítem está sujeto a una licencia Creative Commons.