On the existence of organometallic palladium(IV) complexes

Authors
Usón Lacal, R.; Royo Gracia, PascualUniversity of Alcalá Author; Forniés, J.; Martínez, F.
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4937
DOI: 10.1016/S0022-328X(00)88130-9
ISSN: 0022-328X
Publisher
Elsevier
Date
1975
Affiliation
Universidad de Alcalá. Departamento de Química Inorgánica
Bibliographic citation
Journal of Organometallic Chemistry, 1975, v. 90, p. 367-374
Keywords
Organometallic palladium(IV) complexes
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/S0022-328X(00)88130-9
Rights
(c) Elsevier, 1975
Access rights
info:eu-repo/semantics/openAccess
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Abstract
The reactions of palladium(II) compounds of the type Cl2PdL2 with bromobis(pentafluorophenyl)thallium(III) has been reexamined. The reported preparation of the organo palladium(IV) complex Cl2Pd(C6F5)2(PPh3)2 could not be repeated, and instead mixtures of binuclear palladium(II) compounds, Cl2Pd(C6F5)2L2, and mononuclear palladium(II) compounds were obtained. The binuclear are transformed into the mononuclear complexes on addition of an excess of ligand L. The chlorine bridging atoms of the binuclear complexes can be replaced by other halogens or pseudohalogens by treatment with salts of the MX type (X = Br, I, SCN).
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