Pentafluorophenyl complexes of cobalt(III) with 1-(diacetylmonoximatoimino)-3-(diacetylmonoximeimino)-propane (dotnH)

Authors
Royo Gracia, PascualUniversity of Alcalá Author; Sancho Royo, José
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4934
DOI: 10.1016/S0022-328X(00)84421-6
ISSN: 0022-328X
Publisher
Elsevier
Date
1977
Affiliation
Universidad de Alcalá. Departamento de Química Inorgánica
Funders
Ministerio de Educación y Ciencia
Bibliographic citation
Journal of Organometallic Chemistry, 1977, v.131, n.3, p.439-444
Keywords
Cobalt(III)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/S0022-328X(00)84421-6
Rights
© Elsevier, 1977
Access rights
info:eu-repo/semantics/openAccess
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Abstract
The treatment of Br2Co(dotnH) with the C6F5MgBr Grignard reagent leads to the isolation of (C6F5)BrCo(dotnH). Substitution reactions of this substances make it possible to isolate neutral complexes ((C6F5)CoX(dotnH) (X = CN-, SCN- I-, NO2-)), mononuclear cationic complexes ([C6F5)Co(dotnH)L]Y (L = H2O, NH3, py; Y = ClO4-, BPh4-) and binuclear cationic complexes ({(C6F5)Co-(dotnH)]2X} +BPh4-(X = CN-,SCN-)). The new complexes were studied by IR, visible-UV and NMR spectroscopy.
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