Bis(pentachlorophenyl)thallium(III) compounds

Authors
Royo Gracia, PascualUniversity of Alcalá Author; Serrano Roche, Ricardo
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4893
DOI: 10.1016/S0022-328X(00)93737-9
ISSN: 0022-328X
Publisher
Elsevier
Date
1977
Affiliation
Universidad de Alcalá. Departamento de Química Inorgánica
Funders
We greatly appreciate financial support from Comisión Asesora de Investigación Científica y Técnica
Bibliographic citation
Journal of Organometallic Chemistry, 1977, v. 136, p. 309-313
Keywords
Bis(pentachlorophenyl)thallium(III)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/S0022-328X(00)93737-9
Rights
(c) Elsevier, 1977
Access rights
info:eu-repo/semantics/openAccess
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Abstract
(C6Cl5)2 TlCl has been prepared from TlCl3 and C6Cl5Li. Derivatives of the type (C6Cl5)2TlX (X = ClO4, 1/2 SO4, CH3COO) have been made by treatment of the (C6Cl5)2TlCl with silver salts. The perchlorate group in (C6Cl5)2TlClO4 is readily displaced by several anions to give (C6Cl5)2TlY (Y = Br, I, CN) complexes containing anions which cannot be introduced with silver salts.
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