Bispentafluorophenyl nickel(II) complexes
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4890DOI: 10.1016/S0020-1693(00)89037-4
ISSN: 0020-1693
Publisher
Elsevier
Date
1978Bibliographic citation
Inorganica Chimica Acta, 1978, v. 30, p. 205-207
Keywords
Bispentafluorophenyl nickel(II)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/S0020-1693(00)89037-4Rights
© Elsevier, 1978
Access rights
info:eu-repo/semantics/openAccess
Abstract
Solutions apparently containing Ni[C6F5)2 are obtained by reaction of anhydrous NiBr2 with [C6- F5]MgBr in THF. The addition of different ligands to these solutions gives four-coordinate nickel(II) complexes of the type (C6F5)2NiL2 [L = PEt3 PBu3, PPh3 AsPh3 SbPh3, OPPh3 OAsPh3, p-Dioxane]. Structural data for these compounds are obtained by visible-UV and 1R spectroscopy and magnetic susceptibility measurements.
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