Cyanomethyl cyclopentadienyl complexes of cobalt

Authors
Royo Gracia, PascualUniversity of Alcalá Author; Sancho Royo, José
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4818
DOI: 10.1016/S0022-328X(00)91925-9
ISSN: 0022-328X
Publisher
Elsevier
Date
1978
Affiliation
Universidad de Alcalá. Departamento de Química Inorgánica
Bibliographic citation
Journal of Organometallic Chemistry, 1978, v. 152, p. 221-223
Keywords
Cyanomethyl cyclopentadienyl complexes of cobalt
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/S0022-328X(00)91925-9
Rights
(c) Elsevier, 1978
Access rights
info:eu-repo/semantics/openAccess
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Abstract
The reactions of the complexes CpCo(CO)L (Cp = cyclopentadienyl, L = CO, PPh3) with ClCH2CN have been investigated. Chloroacetonitrile reacts with CpCo(CO)PPh3 to give the cationic complex [CpCo(CH2CN)(CNCH2Cl)PPh3]+, which has been isolated and characterized. Compounds of the type [CpCo(CH2CN)(bipy)]+ BPh4− and CpCo(CH2CN)PPh3CN have been obtained by substitution reactions.
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